Light-Harvesting Metal-Organic Frameworks (MOFs) La-PTC for Photocatalytic Dyes Degradation
A novel porous metal organic framework, La-PTC was synthesized by solvothermal method using a perylene-3,4,9,10-tetracarboxylate ligand and lanthanum metal ion. The FTIR analysis showed that La-PTC has a different structure with PTCDA and Na4PTC. The La-PTC MOF has high crystallinity, bandgap energy...
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| Format: | EJournal Article |
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Department of Chemical Engineering - Diponegoro University,
2021-03-31.
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| LEADER | 02403 am a22002773u 4500 | ||
|---|---|---|---|
| 001 | BCREC_UNDIP_10309_5303 | ||
| 042 | |a dc | ||
| 100 | 1 | 0 | |a Zulys, Agustino |e author |
| 700 | 1 | 0 | |a Adawiah, Adawiah |e author |
| 700 | 1 | 0 | |a Gunlazuardi, Jarnuzi |e author |
| 700 | 1 | 0 | |a Yudhi, Muhammad Derry Luthfi |e author |
| 245 | 0 | 0 | |a Light-Harvesting Metal-Organic Frameworks (MOFs) La-PTC for Photocatalytic Dyes Degradation |
| 260 | |b Department of Chemical Engineering - Diponegoro University, |c 2021-03-31. | ||
| 500 | |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/10309 | ||
| 520 | |a A novel porous metal organic framework, La-PTC was synthesized by solvothermal method using a perylene-3,4,9,10-tetracarboxylate ligand and lanthanum metal ion. The FTIR analysis showed that La-PTC has a different structure with PTCDA and Na4PTC. The La-PTC MOF has high crystallinity, bandgap energy of 2.21 eV with a maximum absorption area at 561 nm. A rod shape structure of La-PTC has been obtained with the surface area of 22.2364 m2.g−1 and classified into mesoporous material. The La-PTC was relative stable up to 376.93 °C. The La-PTC can degrade 64.76% of MO within ca. 240 min under visible light irradiation with the amount of 30 mg La-PTC. The addition of H2O2 improved the photocatalytic activity of La-PTC with degradation efficiency of 67.02%, 70.00%, and 99.60% for MB, RhB, and MO, respectively. This study presents the fabrication of the light-harvesting metal organic framework, La-PTC and its potential in dyes degradation. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). | ||
| 540 | |a Copyright (c) 2021 by Authors, Published by BCREC Group | ||
| 540 | |a https://creativecommons.org/licenses/by-sa/4.0 | ||
| 546 | |a eng | ||
| 690 | |a Metal-organic frameworks; lanthanum; perylene; dyes degradation; photocatalytic | ||
| 655 | 7 | |a info:eu-repo/semantics/article |2 local | |
| 655 | 7 | |a info:eu-repo/semantics/publishedVersion |2 local | |
| 655 | 7 | |2 local | |
| 786 | 0 | |n Bulletin of Chemical Reaction Engineering & Catalysis; 2021: BCREC Volume 16 Issue 1 Year 2021 (March 2021); 170-178 | |
| 786 | 0 | |n 1978-2993 | |
| 787 | 0 | |n https://ejournal2.undip.ac.id/index.php/bcrec/article/view/10309/5303 | |
| 856 | 4 | 1 | |u https://ejournal2.undip.ac.id/index.php/bcrec/article/view/10309/5303 |z Get Fulltext |