Photocatalytic Degradation of Remazol Brilliant Blue R and Remazol Yellow FG using TiO2 doped Cd, Co, Mn

TiO2 and TiO2 doped Cd, Co, Mn (TiO2-M) were synthesized with a sol-gel method, and the photocatalytic activity of Remazol Brilliant Blue R and Remazol Yellow FG has been conducted. TiO2-M (Cd, Co, Mn) was synthesized with the mol Ti:M ratio of 3:1, and the materials were calcined at 300, 400, and 5...

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Main Authors: Purnawan, Candra (Author), Wahyuningsih, Sayekti (Author), Aniza, Oktaviani Nur (Author), Sari, Octaria Priwidya (Author)
Format: EJournal Article
Published: Department of Chemical Engineering - Diponegoro University, 2021-12-20.
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LEADER 03097 am a22002773u 4500
001 BCREC_UNDIP_11423_6246
042 |a dc 
100 1 0 |a Purnawan, Candra  |e author 
700 1 0 |a Wahyuningsih, Sayekti  |e author 
700 1 0 |a Aniza, Oktaviani Nur  |e author 
700 1 0 |a Sari, Octaria Priwidya  |e author 
245 0 0 |a Photocatalytic Degradation of Remazol Brilliant Blue R and Remazol Yellow FG using TiO2 doped Cd, Co, Mn 
260 |b Department of Chemical Engineering - Diponegoro University,   |c 2021-12-20. 
500 |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/11423 
520 |a TiO2 and TiO2 doped Cd, Co, Mn (TiO2-M) were synthesized with a sol-gel method, and the photocatalytic activity of Remazol Brilliant Blue R and Remazol Yellow FG has been conducted. TiO2-M (Cd, Co, Mn) was synthesized with the mol Ti:M ratio of 3:1, and the materials were calcined at 300, 400, and 500 °C. The materials were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX), and UV-Vis Reflectance. The XRD result shows that at the temperature of 300 °C TiO2 and TiO2-M formed tend to be amorphous. At 400 °C the anatase phase is formed, while at 500 °C the rutile phase begins to form. And overall, the crystallinity of TiO2 is higher than metal-doped TiO2. The UV-Vis Reflectance result showed that the bandgap energy of all doping materials (TiO2-M) decreased. The larger the metal ion radius of dopant, the larger the crystal size obtained  and then the higher the bandgap obtained. The results of SEM-EDX showed that the morphology of TiO2 was spherical and regular, whereas the morphology of TiO2-M had a smoother surface due to the influence of metal doping. Photocatalytic activity of TiO2-M on Remazol Brilliant Blue R and Remazol Yellow FG was greater than TiO2. The optimum pH of the solution was obtained at pH 5 and the optimum catalyst phase was obtained at the anatase phase. The percentages degradation for 30 min of Remazol Brilliant Blue R were 67.34% (TiO2), 92.12% (TiO2-Co), 85.47% (TiO2-Mn), and 83.91% (TiO2-Cd), while for Remazol Yellow FG they were 58.84% (TiO2), 74.61% (TiO2-Co), 67.93% (TiO2-Mn) and 64.19% (TiO2-Cd), respectively. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).  
540 |a Copyright (c) 2021 by Authors, Published by BCREC Group 
540 |a https://creativecommons.org/licenses/by-sa/4.0 
546 |a eng 
690 |a Degradation; Remazol Brilliant Blue R; Remazol Yellow FG,;TiO2; TiO2-M (Cd, Co, Mn) 
655 7 |a info:eu-repo/semantics/article  |2 local 
655 7 |a info:eu-repo/semantics/publishedVersion  |2 local 
655 7 |2 local 
786 0 |n Bulletin of Chemical Reaction Engineering & Catalysis; 2021: BCREC Volume 16 Issue 4 Year 2021 (December 2021); 804-815 
786 0 |n 1978-2993 
787 0 |n https://ejournal2.undip.ac.id/index.php/bcrec/article/view/11423/6246 
856 4 1 |u https://ejournal2.undip.ac.id/index.php/bcrec/article/view/11423/6246  |z Get Fulltext