Catalytic Properties of Alumina-Supported Ruthenium, Platinum, and Cobalt Nanoparticles towards the Oxidation of Cyclohexane to Cyclohexanol and Cyclohexanone
A series of metal-loaded (Ru, Pt, Co) alumina catalysts were evaluated for the catalytic oxidation of cyclohexane using tertbutylhydroperoxide (TBHP) as oxidant and acetonitrile or acetic acid as solvent. These materials were prepared by the impregnation method and then characterized by Inductively...
Saved in:
| Main Authors: | , |
|---|---|
| Other Authors: | |
| Format: | EJournal Article |
| Published: |
Department of Chemical Engineering - Diponegoro University,
2018-04-02.
|
| Subjects: | |
| Online Access: | Get Fulltext Get Fulltext Get Fulltext |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| LEADER | 02545 am a22003133u 4500 | ||
|---|---|---|---|
| 001 | BCREC_UNDIP_1226_1271 | ||
| 042 | |a dc | ||
| 100 | 1 | 0 | |a Rekkab-Hammoumraoui, Ilhem |e author |
| 100 | 1 | 0 | |a Algerian Ministry of Higher Education and Scientific Research |e contributor |
| 700 | 1 | 0 | |a Choukchou-Braham, Abderrahim |e author |
| 245 | 0 | 0 | |a Catalytic Properties of Alumina-Supported Ruthenium, Platinum, and Cobalt Nanoparticles towards the Oxidation of Cyclohexane to Cyclohexanol and Cyclohexanone |
| 260 | |b Department of Chemical Engineering - Diponegoro University, |c 2018-04-02. | ||
| 500 | |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1226 | ||
| 520 | |a A series of metal-loaded (Ru, Pt, Co) alumina catalysts were evaluated for the catalytic oxidation of cyclohexane using tertbutylhydroperoxide (TBHP) as oxidant and acetonitrile or acetic acid as solvent. These materials were prepared by the impregnation method and then characterized by Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES), H2 chemisorption, Fourier Transformed Infrared Spectroscopy (FTIR), High-Resolution Transmission Electron Microscopy (HRTEM), and X-ray Diffraction (XRD). All the prepared materials acted as efficient catalysts. Among them, Ru/Al2O3 was found to have the best catalytic activity with enhanced cyclohexane conversion of 36 %, selectivity to cyclohexanol and cyclohexanone of 96 % (57.6 mmol), and cyclohexane turnover frequency (TOF) of 288 h-1. | ||
| 540 | |a Copyright (c) 2018 by Authors, Published by BCREC Group | ||
| 540 | |a http://creativecommons.org/licenses/by-sa/4.0 | ||
| 546 | |a eng | ||
| 690 | |a Cyclohexane oxidation, Alumina, TBHP, Metal. | ||
| 655 | 7 | |a info:eu-repo/semantics/article |2 local | |
| 655 | 7 | |a info:eu-repo/semantics/publishedVersion |2 local | |
| 655 | 7 | |2 local | |
| 786 | 0 | |n Bulletin of Chemical Reaction Engineering & Catalysis; 2018: BCREC Volume 13 Issue 1 Year 2018 (April 2018); 24-35 | |
| 786 | 0 | |n 1978-2993 | |
| 787 | 0 | |n https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1226/1271 | |
| 787 | 0 | |n https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/1226/236 | |
| 787 | 0 | |n https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/1226/237 | |
| 856 | 4 | 1 | |u https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1226/1271 |z Get Fulltext |
| 856 | 4 | 1 | |u https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/1226/236 |z Get Fulltext |
| 856 | 4 | 1 | |u https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/1226/237 |z Get Fulltext |