Structural Investigation: Anionic Polymerization of Acrylamide under Microwave Irradiation using Maghnite-Na+ Clay (Algerien MMT) as Initiator

Intercalation of acrylamide into interlayer spaces of natural  montmorillonite called maghnite (Algerian MMT) by the free solvent polymerization technique under micowave irradiation was studied. The transformation was carried out with using both the raw (Maghnite-Na fin) and treated clay (Maghnite-N...

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Main Authors: Rahmouni, Abdelkader (Author), Belbachir, Mohammed (Author), Ayat, Molkheir (Author)
Format: EJournal Article
Published: Department of Chemical Engineering - Diponegoro University, 2018-08-01.
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001 BCREC_UNDIP_1308_1484
042 |a dc 
100 1 0 |a Rahmouni, Abdelkader  |e author 
100 1 0 |e contributor 
700 1 0 |a Belbachir, Mohammed  |e author 
700 1 0 |a Ayat, Molkheir  |e author 
245 0 0 |a Structural Investigation: Anionic Polymerization of Acrylamide under Microwave Irradiation using Maghnite-Na+ Clay (Algerien MMT) as Initiator 
260 |b Department of Chemical Engineering - Diponegoro University,   |c 2018-08-01. 
500 |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1308 
520 |a Intercalation of acrylamide into interlayer spaces of natural  montmorillonite called maghnite (Algerian MMT) by the free solvent polymerization technique under micowave irradiation was studied. The transformation was carried out with using both the raw (Maghnite-Na fin) and treated clay (Maghnite-Na+ fin) in aqueous sodium hydroxide NaOH solution (1 M). It was shown that no initial modification of the layered mineral (by ion-exchange with Na+ cations or organophilization) is needed for the successful introduction of anionic hydrogels into the interlayer gallery. The goal of the present study was to synthesis anionic polyacrylamide/Maghnite composite with similar composition and structure to that synthesized of other catalyst. The Maghnite catalyst has a significant role in the industrial scale. In fact, the use of Maghnite is preferred for its many advantages: a very low purchase price compared to other catalysts, the easy removal of the reaction mixture. The anionic sodium-clay polyacrylamide material exhibited a tendency to the formation of exfoliated structure. The synthesized hydrogels, as monitored by the swelling behavior, were characterized by Fourier transform infrared and 1HNMR analysis.  
540 |a Copyright (c) 2018 by Authors, Published by BCREC Group 
540 |a http://creativecommons.org/licenses/by-sa/4.0 
546 |a eng 
690 |a green catalysis; Anionic polyacrylamide; hydrogel; Maghnite-H+; Microwave irradiation 
655 7 |a info:eu-repo/semantics/article  |2 local 
655 7 |a info:eu-repo/semantics/publishedVersion  |2 local 
655 7 |2 local 
786 0 |n Bulletin of Chemical Reaction Engineering & Catalysis; 2018: BCREC Volume 13 Issue 2 Year 2018 (August 2018); 262-274 
786 0 |n 1978-2993 
787 0 |n https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1308/1484 
856 4 1 |u https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1308/1484  |z Get Fulltext