Simulation Study of a Membrane Reactor for Ultrapure Hydrogen Recovery from Methanol Steam Reforming Reaction under Periodic Steady-State

Steam reforming of methanol over Cu/ZnO/Al2O3 catalyst was theoretically studied under created unsteady state. A mathematical approach was proposed to evaluate the effect of periodic inputs on reactor performance. The efficacy of the periodic separating reactor in term of pure hydrogen and of methan...

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Bibliographic Details
Main Author: Chibane, Lemnouer (Author)
Other Authors: University Ferhat Abbas Sétif 1, and the Ministry of Higher Education and Scientific Research (Algeria) (Contributor)
Format: EJournal Article
Published: Department of Chemical Engineering - Diponegoro University, 2018-08-01.
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Summary:Steam reforming of methanol over Cu/ZnO/Al2O3 catalyst was theoretically studied under created unsteady state. A mathematical approach was proposed to evaluate the effect of periodic inputs on reactor performance. The efficacy of the periodic separating reactor in term of pure hydrogen and of methanol conversion was measured during the reaction of methanol steam reforming. The obtained results showed that under certain operating conditions the periodic operation can be used advantageously to increase the reactor ability up to a level higher than the maximal steady-state. Moreover, our findings showed that the pumping of hydrogen through the membrane was stimulated by the effect of periodic operations. The predicted results suggested that the created unsteady state mode by using a square wave function could give the better performances compared to the sinusoidal mode. 
Item Description:https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1340