Synthesis and Structure of 2D Cobalt(II)-tartrate Hydrate Coordination Polymers Crystallised from Aqueous Solution

Cobalt(II)-tartrate hydrate coordination polymer is successfully crystallisedfrom aqueous solution at room temperature. Unlike previous methods, diammonium tartrate was used and reacted directly with an aqueous solution of cobalt(II). Single crystal X-ray and ATR-IR analyses were performed toward th...

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Main Authors: Khunur, Mohammad Misbah (Author), Prananto, Yuniar Ponco (Author)
Other Authors: Chemistry Department, Brawijaya University (Contributor)
Format: EJournal Article
Published: Department of Chemical Engineering - Diponegoro University, 2018-08-01.
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042 |a dc 
100 1 0 |a Khunur, Mohammad Misbah  |e author 
100 1 0 |a Chemistry Department, Brawijaya University  |e contributor 
700 1 0 |a Prananto, Yuniar Ponco  |e author 
245 0 0 |a Synthesis and Structure of 2D Cobalt(II)-tartrate Hydrate Coordination Polymers Crystallised from Aqueous Solution 
260 |b Department of Chemical Engineering - Diponegoro University,   |c 2018-08-01. 
500 |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1342 
520 |a Cobalt(II)-tartrate hydrate coordination polymer is successfully crystallisedfrom aqueous solution at room temperature. Unlike previous methods, diammonium tartrate was used and reacted directly with an aqueous solution of cobalt(II). Single crystal X-ray and ATR-IR analyses were performed toward the synthesized crystal. The crystal structure displaysa (6,3) 2D sheet which then grow into a 3D hydrogen-bonded network. Tetra- and hexa-dentate dianionic tartaric ligands are observed in the crystal structure, in which the hexadentate ligand connects four different cobalt centres. This method is considered feasible, affordable, and simple for the production of functional polymeric cobalt(II)-tartrate hydrate.  
540 |a Copyright (c) 2018 by Authors, Published by BCREC Group 
540 |a http://creativecommons.org/licenses/by-sa/4.0 
546 |a eng 
690 |a Diammonium tartrate; coordination polymers; aqueous solution; crystal structure; cobalt(II) tartrate. 
655 7 |a info:eu-repo/semantics/article  |2 local 
655 7 |a info:eu-repo/semantics/publishedVersion  |2 local 
655 7 |2 local 
786 0 |n Bulletin of Chemical Reaction Engineering & Catalysis; 2018: BCREC Volume 13 Issue 2 Year 2018 (August 2018); 213-219 
786 0 |n 1978-2993 
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