Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil

Biofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydro...

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Main Authors: Mirzayanti, Yustia Wulandari (Author), Kurniawansyah, Firman (Author), Prayitno, Danawati Hari (Author), Roesyadi, Achmad (Author)
Format: EJournal Article
Published: Department of Chemical Engineering - Diponegoro University, 2018-04-02.
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001 BCREC_UNDIP_1508_1342
042 |a dc 
100 1 0 |a Mirzayanti, Yustia Wulandari  |e author 
100 1 0 |e contributor 
700 1 0 |a Kurniawansyah, Firman  |e author 
700 1 0 |a Prayitno, Danawati Hari  |e author 
700 1 0 |a Roesyadi, Achmad  |e author 
245 0 0 |a Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil 
260 |b Department of Chemical Engineering - Diponegoro University,   |c 2018-04-02. 
500 |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1508 
520 |a Biofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydrocracking process has been applied in this study to crack Ceiba pentandra oil into a gasoil range hydrocarbon using Zn-Mo/HZSM-5 as a catalyst. The effect of various reaction temperature on the catalytic hydrocracking of Ceiba pentandra oil were studied. The Zn-Mo/HZSM-5 catalyst with metal ratio was prepared by incipient wetness impregnation method. This process used slurry pressure batch reactor with a mechanical stirrer. A series of experiments were carried out in the temperature range from 300-400 oC for 2 h at pressure between 10-15 bar. The conversion and selectivity were estimated. The liquid hydrocarbon product were identified to gasoline, kerosene, and gas oil. The results show that the use of Zn-Mo/HZSM-5 can produce gas oil as the most component in the product. Overall, the highest conversion and selectivity of gas oil range hydrocarbon was obtained when the ZnMo/HZSM-5 metal ratio was Zn(2.86 wt.%)-Mo(5.32 wt.%)/HZSM-5 and the name is Zn-Mo/HZSM-5_102. The highest conversion was obtained at 63.31 % and n-paraffin (gas oil range) selectivity was obtained at 90.75 % at a temperature of 400 oC. Ceiba pentandra oil can be recommended as the source of inedible vegetable oil to produce gasoil as an environmentally friendly transportation fuel.  
540 |a Copyright (c) 2018 by Authors, Published by BCREC Group 
540 |a https://creativecommons.org/licenses/by-sa/4.0 
546 |a eng 
690 |a catalytic hydrocracking; Ceiba pentandra oil; ZincMo/HZSM-5 catalyst; liquid hydrocarbon 
655 7 |a info:eu-repo/semantics/article  |2 local 
655 7 |a info:eu-repo/semantics/publishedVersion  |2 local 
655 7 |2 local 
786 0 |n Bulletin of Chemical Reaction Engineering & Catalysis; 2018: BCREC Volume 13 Issue 1 Year 2018 (April 2018); 136-143 
786 0 |n 1978-2993 
787 0 |n https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1508/1342 
856 4 1 |u https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1508/1342  |z Get Fulltext