Microwave-Assisted Synthesis of DUT-52 and Investigation of Its Photoluminescent Properties
A zirconium metal-organic framework (MOF) of DUT-52 (DUT: Dresden University of Technology) was synthesized herein by reacting zirconium tetrachloride (ZrCl4) and 2,6-naphthalenedicarboxylic acid (H2NDC) in DMF under microwave heating at 115 oC for 25 min. This synthetic procedure was more efficient...
Saved in:
Main Authors: | , , |
---|---|
Other Authors: | |
Format: | EJournal Article |
Published: |
Department of Chemical Engineering - Diponegoro University,
2019-04-15.
|
Subjects: | |
Online Access: | Get Fulltext |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | A zirconium metal-organic framework (MOF) of DUT-52 (DUT: Dresden University of Technology) was synthesized herein by reacting zirconium tetrachloride (ZrCl4) and 2,6-naphthalenedicarboxylic acid (H2NDC) in DMF under microwave heating at 115 oC for 25 min. This synthetic procedure was more efficient than a solvothermal method, by which a long thermal exposure (24 h) of 100-150 oC was required to produce the same MOF. The MOF has a thermal stability of 560 °C, prior to partial loss of interconnected 2,6-naphthalenedicarboxylate (NDC) linkers at some structure building units (SBU). Crystallinity of this DUT-52 was ca. 77 %, which was the same as one synthesized solvothermally. Diffuse Reflectance UV-Vis spectra revealed an absorption at λex of 287 nm, which was equivalent to a bandgap energy of 4.32 eV. Electron excitations of this DUT-52 at 275 and 300 nm gave emission wavelength of 433 nm (a purple region), indicating a prospective use of DUT-52 as a photoluminescent material. |
---|---|
Item Description: | https://ejournal2.undip.ac.id/index.php/bcrec/article/view/2369 |