One-Pot Synthesis of Bi/Fe3O4 and Its Catalytic Performances for 4-Nitrophenol Reduction

A novel approach was successfully developed for the catalyst Bi-deposited Fe3O4 magnetic nanoparticles, which was used in the degradation of 4-nitrophenol (4-NP). The Bi/Fe3O4 composite was prepared via a one-pot process from ferrous sulfate and bismuth chloride using hydrazine hydrate as a reducing...

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Main Authors: Cai, Ke-ying (Author), Liu, Yu-Sheng (Author), Xu, Yang (Author), Zhou, Huimin (Author), Zhang, Lingxia (Author), Cui, Yao (Author)
Format: EJournal Article
Published: Department of Chemical Engineering - Diponegoro University, 2017-04-30.
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001 BCREC_UNDIP_621_675
042 |a dc 
100 1 0 |a Cai, Ke-ying  |e author 
100 1 0 |e contributor 
700 1 0 |a Liu, Yu-Sheng  |e author 
700 1 0 |a Xu, Yang  |e author 
700 1 0 |a Zhou, Huimin  |e author 
700 1 0 |a Zhang, Lingxia  |e author 
700 1 0 |a Cui, Yao  |e author 
245 0 0 |a One-Pot Synthesis of Bi/Fe3O4 and Its Catalytic Performances for 4-Nitrophenol Reduction 
260 |b Department of Chemical Engineering - Diponegoro University,   |c 2017-04-30. 
500 |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/621 
520 |a A novel approach was successfully developed for the catalyst Bi-deposited Fe3O4 magnetic nanoparticles, which was used in the degradation of 4-nitrophenol (4-NP). The Bi/Fe3O4 composite was prepared via a one-pot process from ferrous sulfate and bismuth chloride using hydrazine hydrate as a reducing agent. The catalyst was characterized by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. In the composite pure Fe3O4 particles were synthesized and bismuth particles were well dispersed. The catalytic performances were investigated for the reduction of 4-NP with sodium borohydride. The catalyst has higher activity when Bi/Fe molar ratio is 1:4 in the composite and the rate constant k is about 0.611 min-1. The catalyst has good reusability which can be used 10 cycles without obvious deactivation. Furthermore, the catalyst can be easily separated by an external magnetic field.  
540 |a Copyright (c) 2017 by Authors, Published by BCREC Group 
540 |a http://creativecommons.org/licenses/by-sa/4.0 
546 |a eng 
690 |a Bismuth; Bi/Fe3O4; 4-Nitrophenol; Reduction 
655 7 |a info:eu-repo/semantics/article  |2 local 
655 7 |a info:eu-repo/semantics/publishedVersion  |2 local 
655 7 |2 local 
786 0 |n Bulletin of Chemical Reaction Engineering & Catalysis; 2017: BCREC Volume 12 Issue 1 Year 2017 (April 2017); 89-95 
786 0 |n 1978-2993 
787 0 |n https://ejournal2.undip.ac.id/index.php/bcrec/article/view/621/675 
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856 4 1 |u https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/621/65  |z Get Fulltext