Hydrocracking of Non-edible Vegetable Oils with Co-Ni/HZSM-5 Catalyst to Gasoil Containing Aromatics

Biofuel has been considered as one of the environmentally friendly energy sources to substitute fossil fuel derived from non-edible vegetable oil. This research aims to investigate the effect of the non-edible vegetable oil composition on a specific hydrocarbons distribution contained in biofuel and...

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Main Authors: Prajitno, Danawati Hari (Author), Roesyadi, Achmad (Author), Al-Muttaqii, Muhammad (Author), Marlinda, Lenny (Author)
Format: EJournal Article
Published: Department of Chemical Engineering - Diponegoro University, 2017-12-01.
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042 |a dc 
100 1 0 |a Prajitno, Danawati Hari  |e author 
100 1 0 |e contributor 
700 1 0 |a Roesyadi, Achmad  |e author 
700 1 0 |a Al-Muttaqii, Muhammad  |e author 
700 1 0 |a Marlinda, Lenny  |e author 
245 0 0 |a Hydrocracking of Non-edible Vegetable Oils with Co-Ni/HZSM-5 Catalyst to Gasoil Containing Aromatics 
260 |b Department of Chemical Engineering - Diponegoro University,   |c 2017-12-01. 
500 |a https://ejournal2.undip.ac.id/index.php/bcrec/article/view/799 
520 |a Biofuel has been considered as one of the environmentally friendly energy sources to substitute fossil fuel derived from non-edible vegetable oil. This research aims to investigate the effect of the non-edible vegetable oil composition on a specific hydrocarbons distribution contained in biofuel and the aromatics formation through hydrocracking reaction with the Co-Ni/HZSM-5 catalyst. The formation of aromatics from non-edible vegetable oils, such as: Cerbera manghas, rubber seed, and sunan candlenut oils, containing saturated, mono- and polyunsaturated fatty acids is presented. The hydrocracking reaction was carried out in a pressure batch reactor, a reaction temperature of 350 oC for 2 h, reactor pressure of 15 bar after flowing H2 for 1 hour, and a catalyst/oil ratio of 1 g/200 mL. Liquid hydrocarbon product was analyzed by gas chromatography-mass spectrometry. Based on the GC-MS analysis, hydrocracking on three different oils indicated that polyunsaturated fatty acids were required to produce relatively high aromatics content. The sunan candlenut oil can be converted to gasoil range hydrocarbons containing a small amount of aromatic through hydrocracking reaction. Meanwhile, the aromatics in liquid product from hydrocracking of Cerbera manghas and rubber seed oils were not found.  
540 |a Copyright (c) 2017 by Authors, Published by BCREC Group 
540 |a http://creativecommons.org/licenses/by-sa/4.0 
546 |a eng 
690 |a hydrocracking; non-edible vegetable oil; aromatics; gasoil; Co-Ni/HZSM-5 catalyst 
655 7 |a info:eu-repo/semantics/article  |2 local 
655 7 |a info:eu-repo/semantics/publishedVersion  |2 local 
655 7 |2 local 
786 0 |n Bulletin of Chemical Reaction Engineering & Catalysis; 2017: BCREC Volume 12 Issue 3 Year 2017 (December 2017); 318-328 
786 0 |n 1978-2993 
787 0 |n https://ejournal2.undip.ac.id/index.php/bcrec/article/view/799/958 
787 0 |n https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/799/110 
856 4 1 |u https://ejournal2.undip.ac.id/index.php/bcrec/article/view/799/958  |z Get Fulltext 
856 4 1 |u https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/799/110  |z Get Fulltext