A Green Heterogeneous Catalyst Production and Characterization for Biodiesel Production using RSM and ANN Approach

In this work, naturally available moringa oleifera leaves (also known as horseradish trees or drumstick trees) are chosen as a heterogeneous catalyst in the transesterification for biodiesel production from palm oil. The dry moringa oleifera leaves are calcinated at 700 °C for 3 hours to improve the...

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Main Authors: Kolakoti, Aditya (Author), Setiyo, Muji (Author), Rochman, Muhammad Latifur (Author)
Format: EJournal Article
Published: Center of Biomass & Renewable Energy, Diponegoro University, 2022-08-04.
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LEADER 02502 am a22002653u 4500
001 IJRED_UNDIP_43627_pdf
042 |a dc 
100 1 0 |a Kolakoti, Aditya  |e author 
700 1 0 |a Setiyo, Muji  |e author 
700 1 0 |a Rochman, Muhammad Latifur  |e author 
245 0 0 |a A Green Heterogeneous Catalyst Production and Characterization for Biodiesel Production using RSM and ANN Approach 
260 |b Center of Biomass & Renewable Energy, Diponegoro University,   |c 2022-08-04. 
500 |a https://ejournal.undip.ac.id/index.php/ijred/article/view/43627 
520 |a In this work, naturally available moringa oleifera leaves (also known as horseradish trees or drumstick trees) are chosen as a heterogeneous catalyst in the transesterification for biodiesel production from palm oil. The dry moringa oleifera leaves are calcinated at 700 °C for 3 hours to improve their adsorbing property. The calcinated catalyst characterization analysis from XRD and EDX highlights the presence of calcium, potassium, and other elements. Response surface method (RSM) optimization and artificial neural network (ANN) modeling were carried out to elucidate the interaction effect of significant process variables on biodiesel yield. The results show that a maximum biodiesel yield of 92.82% was achieved at optimum conditions of catalyst usage (9 wt.%), molar ratio, methanol to triglyceride (7:1), temperature (50 °C) and reaction time (120 min). The catalyst usage (wt.%) was identified as a significant process variable, followed by the molar ratio. Furthermore, the biodiesel's significant fuel properties in terms of thermal, physical, chemical, and elemental match the established standards of ASTM. Finally, when the catalyst was reused for five cycles, more than 50% of the biodiesel yield was achieved. 
540 |a Copyright (c) 2022 The Author(s). Published by Centre of Biomass and Renewable Energy (CBIORE) 
540 |a https://creativecommons.org/licenses/by-sa/4.0 
546 |a eng 
690 |a Moringa oleifera leaves; Calcination; Biodiesel; Optimization and Modeling 
655 7 |a info:eu-repo/semantics/article  |2 local 
655 7 |a info:eu-repo/semantics/publishedVersion  |2 local 
655 7 |2 local 
786 0 |n International Journal of Renewable Energy Development; Vol 11, No 3 (2022): August 2022; 703-712 
786 0 |n 2252-4940 
787 0 |n https://ejournal.undip.ac.id/index.php/ijred/article/view/43627/pdf 
856 4 1 |u https://ejournal.undip.ac.id/index.php/ijred/article/view/43627/pdf  |z Get Fulltext