Synthesis and Applications of New Spin Crossover Compounds

The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials-promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscle...

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Bibliographic Details
Main Author:	Kitazawa, Takafumi (auth)
Format:	Book Chapter
Published:	MDPI - Multidisciplinary Digital Publishing Institute 2019
Subjects:	n/a hexadentate ligand X-ray diffraction structural disorder lattice energy 2-bis(4-pyridyl)ethane thermal hysteresis optical conductivity spectrum spin-state crossover solvate single crystal spin-crossover transition spin-crossover cobalt oxide amorphous metal dithiolene complexes qsal ligand impurity effect 3-triazole intermolecular interactions spin crossover hydrogen bonding 1 2 optical microscopy supramolecular coordination polymer paramagnetic ligand magnetic susceptibility high spin [Fe(III)(3-OMesal2-trien)]+ aminoxyl cobalt(II) ion mosaicity Fe(III) coordination complexes nitroxides C-H···? interactions Fe(II) dithiooxalato ligand dinuclear triple helicate coordination polymers magnetization spiral structure magnetostructural correlations charge-transfer phase transition structure phase transition magnetic properties spin polaron substitution of 3d transition metal ion iron(II) complexes X-ray absorption spectroscopy coordination complexes crystal engineering fatigability soft X-ray induced excited spin state trapping spin transition dipyridyl-N-alkylamine ligands coordination polymer iron (II) iron mixed-valence complex chiral propeller structure spin cross-over (SCO) EPR spectroscopy Cu(II) complexes solvent effects ferromagnetism SQUID LIESST effect low spin (LS) 57Fe Mössbauer spectroscopy dielectric response iron(II) hetero metal complex atropisomerism switch Schiff base counter-anion DFT calculation Fe(III) complex Fe(II) complex high spin (HS) reaction diffusion thermochromism supramolecular isomerism phase transition magnetic transition mononuclear [Au(dmit)2]? UV-Vis spectroscopy phase transitions ?-? interactions [Au(dddt)2]? crystal structure linear pentadentate ligand ion-pair crystals
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Synthesis and Applications of New Spin Crossover Compounds

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